6,6′-Dieth­oxy-2,2′-[4,5-dimethyl-o-phenyl­enebis(nitrilo­methyl­idyne)]diphenol–ethanol–water (1/1/1)

نویسندگان

  • Hadi Kargar
  • Reza Kia
  • Arezoo Jamshidvand
  • Hoong-Kun Fun
چکیده

The title bis-Schiff base compound, C(26)H(28)N(2)O(4)·C(2)H(6)O·H(2)O, crystallizes as an ethanol and water solvate. Strong intra-molecular O-H⋯N hydrogen bonds generate S(6) ring motifs. The water H atoms form bifurcated O-H⋯(O,O) inter-molecular hydrogen bonds with the O atoms of the hydroxyl and eth-oxy groups with R(1) (2)(5) ring motifs, which may, in part, influence the mol-ecular configuration. The dihedral angles between the central benzene ring and the two outer benzene rings of the Schiff base mol-ecule are 5.64 (8) and 44.78 (9)°. The crystal structure is further stabilized by inter-molecular C-H⋯O and π-π inter-actions [centroid-centroid distances = 3.6139 (11)-3.7993 (11) Å].

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عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009